Because the smart alternator cuts off charging when there's an excess of charge in the starter battery to reduce the load on the engine, in a split charge relay system every time the alternator shuts off the leisure battery can suffer from not getting enough charge. Often the van will only charge to 80% to allow for regeneration charging.
A DC-DC charger gets around this and makes sure it charges fully.
If you want to make best use of your leisure battery's reserves, a DC-DC charger is the best way forward. Plus, if you decide to go lithium in the future when the lead acid leisure battery dies, so long as you get one that will work with lithium, it's a simple setting change to get it to work ( and get twice as much capacity to boot)
You could try unplugging the shunt connection, this puts the van into normal charging mode and may solve your undercharging leisure battery problem, but it will light the MIL on your dash because it thinks something is wrong.