So I've used the thick red wire, it's a 16mm2 wire, but annoyingly it's fused to two other thick wires that run off to two separate mini fuse boxes. In my case, I had a 20A fuse for the cigarette lighter and another 10A fuse in the other which I think is for occupancy detection (but could be wrong).
VW wired this really weirdly, with wires taped together and it just seemed really inefficient. I tidied it up and moved both fuses to the one big fuse box where the cigarette lighter fuse is. Here there are two thick red wires - one feeds 6 fuse positions and the other just goes to the first pin, but seemingly for no reason so I removed that wire. I moved the 10A fuse onto that fed rail and moved the blue/red wire to the fuse.
I now have two thick red wires, one from the starter battery fuse box and the other going to the fusebox. I have connected both of these together, and they go to the input fuse for my DCDC charger.
Now one fuse box:
View attachment 315478